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جذب آمونیوم از محلولهای آبی بوسیله نانو ذرات اکسید آهن سنتز شده با عصاره اکالیپتوس گلوبلوس | ||
تحقیقات کاربردی خاک | ||
دوره 11، شماره 2، شهریور 1402، صفحه 1-12 اصل مقاله (1.08 M) | ||
نوع مقاله: مقاله پژوهشی | ||
نویسندگان | ||
احسان خوش کلام1؛ امیر فتوت* 2؛ اکرم حلاج نیا3؛ حسین عشقی4 | ||
1گروه علوم خاک، دانشکده کشاورزی، دانشگاه فردوسی مشهد | ||
2استاد گروه علوم خاک، دانشکده کشاورزی، دانشگاه فردوسی مشهد | ||
3استادیار گروه علوم خاک دانشکده کشاورزی دانشگاه فردوسی مشهد | ||
4استاد گروه شیمی، دانشکده علوم، دانشگاه فردوسی مشهد | ||
چکیده | ||
مصرف بیرویه کودهای آمونیومی، موجب ورود این نوع از آلاینده به اکوسیسیتم آبی و غنی شدن منابع آب میگردد. در این پژوهش، جذب آمونیوم از محلولهای آبی بوسیله نانو ذرات اکسید آهن سنتز شده به روش شیمی سبز با استفاده از عصاره برگ اکالیپتوس گلوبلوس (EL-Fe NPs) ، به عنوان روشی جدید، سازگار با محیط زیست و مقرون به صرفه، بررسی شد. خصوصیات نانو ذرات توسط میکروسکوپ الکترونی عبوری (TEM)، طیف سنج پراش پرتو ایکس (XRD) و طیف سنج تبدیل فوریه مادون قرمز (FT-IR) تعیین شد. اثر زمان تماس (0- 120 دقیقه)، pH (3- 11) و نمک KCl به عنوان محلول زمینه بر جذب آمونیوم مورد بررسی قرار گرفت. دادههای حاصل از جذب آمونیوم توسط مدلهای سینتیکی برازش داده شدند. در شرایط pH تعادلی 7/3 جذب آمونیوم توسط EL-Fe NPs بعد از گذشت 30 دقیقه به تعادل رسید. در این مدت زمان، از غلظت اولیه 10 میلیگرم بر لیتر آمونیوم، حدود 86/11% درصد آن توسط 5/1 گرم بر لیتر از نانو ذرات جذب شد. طبق نتایج، حذف آمونیوم تحت تاثیر pH و قدرت یونی (KCl) قرار داشت. به طوریکه در 8/7= pH حداکثر میزان جذب آلاینده (9/76 %) اتفاق افتاد. همچنین، افزایش قدرت یونی منجر به کاهش جذب آمونیوم گردید. به صورتیکه، در قدرت یونیهای 0، 001/0، 01/0 و 1/0 مولار KCl، میزان جذب به ترتیب 9/76، 2/64، 2/28 و 5 درصد بود. سینتیک جذب آمونیوم از معادله شبه مرتبه دوم تبعیت کرد (998/0 = r2). با توجه به اثر افزایش قدرت یونی در کاهش میزان جذب و همچنین وابسته بودن جذب آمونیوم به pH، انتظار میرود که واکنش بین آمونیوم و EL-Feb NPs به احتمال زیاد از طریق الکترواستاتیک باشد. طبق نتایج، بهنظر میرسد جذب آمونیوم توسط EL-Fe NPs تحت تاثیر شیمی محلول قرار دارد. | ||
کلیدواژهها | ||
اکالیپتوس گلوبلوس؛ آلودگی آب؛ جذب آمونیوم؛ شیمی سبز؛ نانو ذرات اکسید آهن | ||
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