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سینتیک کاهش هیدروکربن های نفتی با زمان در خاک تیمار شده با بیوچار کاه و کلش گندم و بقایای بستر قارچ | ||
| تحقیقات کاربردی خاک | ||
| مقاله 3، دوره 14، شماره 1، خرداد 1405، صفحه 31-50 اصل مقاله (770.45 K) | ||
| نوع مقاله: مقاله پژوهشی | ||
| شناسه دیجیتال (DOI): 10.30466/asr.2026.56232.1888 | ||
| نویسندگان | ||
| هاجر مریخ پور* 1؛ نفیسه نورمحمدی2 | ||
| 1دانشیار دانشکده مهندسی عمران، آب و محیط زیست، دانشگاه شهید بهشتی، تهران، ایران | ||
| 2پژوهشکده بیوتکنولوژی متابولیتهای ثانویه اصفهان، سازمان آموزش و تحقیقات کشاورزی ایران | ||
| چکیده | ||
| بیوچارها در مقایسه با سایر اصلاحکنندههای خاک، بهدلیل ویژگیهای ذاتی مانند تخلخل بالا، سطح ویژه زیاد و وجود گروههای عاملی فعال ، پتانسیل قابلتوجهی در بهبود خاکهای آلوده دارند. این پژوهش با هدف بررسی سینتیک کاهش آلودگی هیدروکربنهای نفتی کل (TPH) در خاک آلوده، تحت تأثیر دو نوع بیوچار شامل کاه و کلش گندم و بقایای بستر قارچ، در سطوح مختلف کاربرد انجام شد. آزمایش در قالب طرح فاکتوریل کاملاً تصادفی با سه فاکتور نوع بیوچار (دو سطح)، سطح کاربرد بیوچار (پنج سطح؛ صفر، ۱۰، ۲۰، ۳۰ و ۵۰ گرم بر کیلوگرم) و زمان انکوباسیون (شش سطح؛ ۶، ۱۲، ۱۸، ۲۴، ۴۲ و ۶۰ روز) در سه تکرار اجرا گردید. غلظت هیدروکربنهای نفتی کل و میزان تنفس میکروبی در فواصل زمانی مشخص اندازهگیری و دادهها با نرمافزار) Rنسخه 5/4( مورد تجزیه و تحلیل قرار گرفت. نتایج آنالیز واریانس دوطرفه نشان داد که هر سه عامل نوع بیوچار، زمان انکوباسیون و اثر متقابل آنها تأثیر معنیداری بر غلظت هیدروکربنهای نفتی کل و تنفس میکروبی داشتند . مقادیر پتانسیل تجزیه و کاهش TPH با استفاده از مدلهای سینتیکی مرتبه اول و مرتبه دوم محاسبه شد. بر اساس نتایج، برای تیمارهای بیوچار کاه و کلش گندم، هر دو مدل دارای برازش قابلقبولی بودند (NRMSE < 5%, R² > 0.94) و. در تیمارهای بیوچار بقایای بستر قارچ، مدلهای مرتبه اول و دوم در سطوح پایینتر بیوچار برازش مناسبی نشان دادند، اما در سطوح بالاتر، دقت برازش کاهش یافت که احتمالاً ناشی از اثرات پیچیدهتر در جذب و تجزیه آلایندهها است. بهطور کلی، نتایج این مطالعه نشان داد که بیوچارها، بهویژه بیوچار بقایای بستر قارچ، موجب افزایش معنیدار نرخ تجزیه زیستی TPH و کاهش نیمهعمر آلایندهها در خاک آلوده میشوند. بنابراین، استفاده از بیوچار بهعنوان یک اصلاحکننده زیستمحیطی مؤثر، پایدار و سازگار با محیطزیست برای کاهش آلودگیهای نفتی و بهبود کیفیت خاکهای آلوده توصیه میشود. | ||
| کلیدواژهها | ||
| هیدروکربن های نفتی؛ بیوچار؛ کاه و کلش گندم؛ بقایای بستر قارچ؛ تابع سینتیکی | ||
| مراجع | ||
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آمار تعداد مشاهده مقاله: 93 تعداد دریافت فایل اصل مقاله: 33 |
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